Cyanide-bridged trinuclear MnIII–FeIII assembly: Crystal structure, magnetic and photoluminescence behavior

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dc.authorid0000-0002-4522-6500en_US
dc.contributor.authorErkarslan, U.
dc.contributor.authorOylumluoğlu, G.
dc.contributor.authorÇoban, M.B.
dc.contributor.authorÖztürk, Esra Çırçır
dc.contributor.authorKara, H.
dc.date.accessioned2019-12-06T20:30:30Z
dc.date.available2019-12-06T20:30:30Z
dc.date.issued2016
dc.departmentKMÜ, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümüen_US
dc.description.abstractA trinuclear cyanide-bridged MnIII–FeIII compound, [NEt4][Mn(3,5-ClL)2(MeOH)]2Fe(CN)6], [3,5-ClLH2 = N,N?-bis(3,5-chlorosalicylidenato)-1,2-diamino propane)], 1, has been characterized by X-ray analyses, magnetic and photoluminescence measurements. The structure assumes a two-dimensional network consisting of Mn–NC–Fe–CN–Mn (Fe1–C19–N4 = 175.9(3)°, C19–N4–Mn1 = 145.5 (3)°). The magnetic properties of this compound indicate antiferromagnetic coupling between low-spin Fe(III) and high-spin Mn(III) through the cyanide bridges. Furthermore, solid state photoluminescence properties of complex 1 have been investigated at room temperature. © 2016 Elsevier B.V.en_US
dc.description.sponsorshipUniversity of Bristol TBAG-108T431 Royal Societyen_US
dc.description.sponsorshipThe authors are grateful to the Scientific and Technological Research Council of Turkey (TUBITAK) (Grant number TBAG-108T431 ) for the financial support. Dr. Kara would like to thank TUBITAK for NATO-B1 and the Royal Society short visit fellowship for financial support and Prof. A. Guy Orpen (School of Chemistry, University of Bristol, UK) for his hospitality. The authors are also very grateful to Dr. Andrea Caneschi and Dr. Lorenzo Sorace (Department of Chemistry, University of Florence) for the SQUID measurements. Appendix Aen_US
dc.identifier.citationErkarslan, U., Oylumluoğlu, G., Çoban, M. B., Öztürk, E., Kara, H. (2016). Cyanide-bridged trinuclear MnIII–FeIII assembly: Crystal structure, magnetic and photoluminescence behavior. Inorganica Chimica Acta, 445, 57-61.
dc.identifier.doi10.1016/j.ica.2016.02.010
dc.identifier.endpage61en_US
dc.identifier.issn0020-1693
dc.identifier.scopus2-s2.0-84966664873
dc.identifier.scopusqualityQ2
dc.identifier.startpage57en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.ica.2016.02.010
dc.identifier.urihttps://hdl.handle.net/11492/2161
dc.identifier.volume445en_US
dc.identifier.wosWOS:000372747600008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorÖztürk, Esra Çırçır
dc.language.isoen
dc.publisherElsevier S.A.en_US
dc.relation.journalInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyano-Bridgeden_US
dc.subjectMagnetismen_US
dc.subjectMnIII–FeIII compounden_US
dc.subjectPhotoluminescenceen_US
dc.subjectX-Ray Analysesen_US
dc.titleCyanide-bridged trinuclear MnIII–FeIII assembly: Crystal structure, magnetic and photoluminescence behavioren_US
dc.typeArticle

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