Synthesis of ruthenium(II) complexes derived from reduced imine ligands: As catalysts for transfer hydrogenation of ketones

dc.authorid0000-0002-4522-6500en_US
dc.contributor.authorDayan, Serkan
dc.contributor.authorKayacı, Nilgün
dc.contributor.authorKalaycıoğlu, Nilgün Ozpozan
dc.contributor.authorDayan, Osman
dc.contributor.authorÖztürk, Esra Çırçır
dc.date.accessioned2019-12-06T21:17:49Z
dc.date.available2019-12-06T21:17:49Z
dc.date.issued2013
dc.departmentKMÜ, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümüen_US
dc.descriptionWOS:000319123700016en_US
dc.description.abstractN-[2-(benzylamino)phenyl]benzenesulfonamide derivatives (1-6) were successfully synthesized by the reaction of imine ligands derived from various N-(2-aminophenyl)benzenesulfonamides and NaBH4. Then, a series of N-coordinate Ru(II) arene complexes 7-12 were prepared from the reaction of [RuCl2(p-cymene)](2) with 1-6. The synthesized compounds were characterized by different methods such as NMR, FT-IR, and elemental analysis. 7-12 were used as catalysts for the transfer hydrogenation (TH) of ketones. At the same time, the effect of various bases such as NaOH, KOH, KOBut and Et3N as organic base were investigated in TH of ketones by 2-propanol as the hydrogen source. 7-12 showed good catalytic activity and so the effects of the different groups were also examined. Crown Copyright (c) 2013 Published by Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipErciyes University (ERUBAP)Erciyes University [FBY-11-3783]en_US
dc.description.sponsorshipWe acknowledge the financial support granted by Erciyes University (ERUBAP), (FBY-11-3783, ID: 3783).en_US
dc.identifier.citationDayan, S., Kayacı, N., Kalaycoğlu Ozpozan, N., Dayan, O., Öztürk ÇırÇır, Esra. (2013). Synthesis of ruthenium(II) complexes derived from reduced imine ligands: As catalysts for transfer hydrogenation of ketones. Inorganica Chimica Acta, Volume 401, 24 May 2013, Pages 107-113.
dc.identifier.doi10.1016/j.ica.2013.03.004
dc.identifier.endpage113en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84877058247
dc.identifier.scopusqualityQ2
dc.identifier.startpage107en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.ica.2013.03.004
dc.identifier.urihttps://hdl.handle.net/11492/3192
dc.identifier.volume401en_US
dc.identifier.wosWOS:000319123700016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorÖztürk, Esra Çırçır
dc.language.isoen
dc.publisherElsevier Science SAen_US
dc.relation.journalInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectRu(II) Complexesen_US
dc.subjectSulfonamideen_US
dc.subjectImineen_US
dc.titleSynthesis of ruthenium(II) complexes derived from reduced imine ligands: As catalysts for transfer hydrogenation of ketonesen_US
dc.typeArticle

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