Investigation of photochemical properties of CeO2:0.1Nd and CeO2:0.05Nd0.05 M(M: Dy, Sm, Tb)

dc.authorid0000-0002-4522-6500en_US
dc.contributor.authorElmas, Fettah
dc.contributor.authorKırkgeçit, Rabia
dc.contributor.authorTorun, Handan Özlü
dc.contributor.authorÖztürk, Esra
dc.date.accessioned2023-03-07T08:49:31Z
dc.date.available2023-03-07T08:49:31Z
dc.date.issued2022en_US
dc.departmentKMÜ, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümüen_US
dc.descriptionWOS:001008758100001en_US
dc.description.abstractThis study examined the effect of different dope types to contribute for the photochemical application area of the CeO2 compound. In addition, the photocatalyst properties of binary and ternary compounds, which vary with the molecular structure of dye species, were reported. For. this purpose, undoped-CeO2. CeO2:0.1Nd and CeO2:0.05Nd0.05 M(Dy,Sm,Tb) compounds were synthesized by a semi-process room temperature(SPRT) method. In characterization studies, X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), Raman, ultraviolet–visible spectroscopy (UV–vis), and photoluminescence spectroscopy (PL) were used. The secondary phase was observed with a 0.05 Tb contribution. The cubic crystal structure was obtained in other compounds. The lowest optical band gap was determined as 2.60 eV in CeO2:0.1Nd compound. In photocatalyst studies, methylene blue(MB), malachite green (MG), and rhodamine-B(RhB) dyes were used. It was observed that the photocatalytic efficiency decreased as the molecular size increased. The highest catalytic efficiency was calculated as 82% for the CeO2:0.1Nd compound for methylene blue. The PL results determined that the doping of Nd3+, Sm3+, Dy3+, and Tb3+ ions played an important role in developing blue, green, and red emission bands for the photoluminescence of CeO2.en_US
dc.identifier.citationElmas, F., Kırkgeçit, R., Torun, H. Ö., Öztürk, E. (2022). Investigation of photochemical properties of CeO2:0.1Nd and CeO2:0.05Nd0.05 M(M: Dy, Sm, Tb). Journal of Photochemistry and Photobiology A: Chemistry, 439.en_US
dc.identifier.doi10.1016/j.jphotochem.2023.114616
dc.identifier.issn1010-6030
dc.identifier.scopus2-s2.0-85148674351
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jphotochem.2023.114616
dc.identifier.urihttps://hdl.handle.net/11492/7060
dc.identifier.volume439en_US
dc.identifier.wosWOS:001008758100001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorÖztürk, Esra
dc.language.isoen
dc.publisherElsevier B.V.en_US
dc.relation.journalJournal of Photochemistry and Photobiology A: Chemistryen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCeO2en_US
dc.subjectCo-Dopingen_US
dc.subjectDye Typeen_US
dc.subjectLanthanideen_US
dc.subjectPhotocatalyticen_US
dc.subjectPhotoluminescenceen_US
dc.titleInvestigation of photochemical properties of CeO2:0.1Nd and CeO2:0.05Nd0.05 M(M: Dy, Sm, Tb)en_US
dc.typeArticle

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