Transition metaleincorporated tungsten-based ternary refractory metal selenides (MWSex; M = Fe, Co, Ni, and Mn) as hydrogen evolution catalysts at soft interfaces

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dc.authorid0000-0003-1463-9764en_US
dc.authorid0000-0002-3935-9649en_US
dc.authorid0000-0002-3689-0469en_US
dc.contributor.authorAslan, E.
dc.contributor.authorSarılmaz, Adem
dc.contributor.authorYanalak, G.
dc.contributor.authorÖzel, Sultan Süleyman
dc.contributor.authorÖzel, Faruk
dc.contributor.authorPatir, I. H.
dc.date.accessioned2021-01-19T10:47:12Z
dc.date.available2021-01-19T10:47:12Z
dc.date.issued2020en_US
dc.departmentKMÜ, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümüen_US
dc.descriptionWOS:000601397500007en_US
dc.description.abstractHydrogen evolution reaction (HER) catalysts including transition metal chalcogenides have been recognized as a class of very promising non-expensive and earth-abundant catalysts. Tremendous investigations on the binary and ternary metal sulfides/selenides have demonstrated extraordinary chemical and physical properties such as good structural stability and adjustable chemical composition. The ternary amorphous refractory metal selenides (MWSex; M = Fe, Co, Ni, Mn) have been synthesized by the hot-injection method. The NiWSex, CoWSex, FeWSex and MnWSex nanostructures have been used as catalysts for the hydrogen evolution at the biphasic systems of water and 1,2-dichloroethane with similar to a biomembrane. The catalytic activity differences of ternary metal selenides have been compared with each other taking into account transition metals which are changed in the order of Fe approximate to Mn << Co < Ni. The catalytic activities of the MWSex have not been changed when adding of Fe and Mn into the tungsten selenide nanostructure, which may be originated from amorphous structures of FeWSex and MnWSex. Ni and Co addition into the tungsten selenide have improved the electrocatalytic HER activity when compared with only WSex.en_US
dc.description.sponsorshipThe authors would like to thank TUBITAK (The Scientific and Technological Research Council of Turkey) (Grant number: 215M309) and Turkish Academy of Sciences via a TUBA-GEBIP fellowship for supporting this work.en_US
dc.identifier.citationAslan, E., Sarılmaz, A., Yanalak, G.,Özel, S. S., Ozel, F.,Patir, I. H.(2020).Transition metaleincorporated tungsten-based ternary refractory metal selenides (MWSex; M = Fe, Co, Ni, and Mn) as hydrogen evolution catalysts at soft interfaces.Materials Today Energy, 18.en_US
dc.identifier.doi10.1016/j.mtener.2020.100510
dc.identifier.issn2468-6069
dc.identifier.scopus2-s2.0-85091261913
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.mtener.2020.100510
dc.identifier.urihttps://hdl.handle.net/11492/4761
dc.identifier.volume18en_US
dc.identifier.wosWOS:000601397500007
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorSarılmaz, Adem
dc.institutionauthorÖzel, Sultan Süleyman
dc.institutionauthorÖzel, Faruk
dc.language.isoen
dc.publisherElsevieren_US
dc.relation.journalMaterials Today Energyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.relation.tubitak215M309
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTernary Metal Selenidesen_US
dc.subjectHydrogen Evolution Reactionen_US
dc.subjectLiquid/Liquid İnterfacesen_US
dc.subjectIron Tungsten Selenideen_US
dc.subjectManganese Tungsten Selenideen_US
dc.titleTransition metaleincorporated tungsten-based ternary refractory metal selenides (MWSex; M = Fe, Co, Ni, and Mn) as hydrogen evolution catalysts at soft interfacesen_US
dc.typeArticle

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