A novel biosorbent functionalized pillar[5]arene: Synthesis, characterization and effective biosorption of Cr(VI)
Yükleniyor...
Dosyalar
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier B.V.
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Among toxic chemicals, hexavalent chromium (Cr(VI)) is one of the most carcinogenic and toxic pollutants that hostiles to the health of both humans and other living things. Therefore, the removal of Cr(VI) is of great importance to keep our environment clean and tidy. In this study, an easy-make, inexpensive, and natural biosorbent material (Sp-P[5]) was prepared to preserve our environment using a pillar[5]arene based-on sporopollenin microcapsule. The prepared biosorbent was successfully characterized by some techniques such as FTIR, XRD, and SEM. The biosorbent, Sp-P[5], exhibited an open mesoporous structure richly decorated with multi-amine-containing moieties resulting in enhanced Cr(VI) sorption. The sorption behavior of Cr(VI) ions is satisfactorily adapted from the sorption kinetics pseudo-second-order law and the isotherm models to the Langmuir model at different temperatures. The Langmuir model fits at different temperatures (298–328 K) and the maximum sorption capacities of the Cr(VI) ion ranged from 106.38 to 117.26 mg/g. The thermodynamic calculations reveal that the sorption of Cr(VI) ions on the Sp-P[5] is entropy-driven, endothermic, and spontaneous. The prepared biosorbent was also applied to the natural wastewater samples and different ions (chromate and dichromate). The sorption and desorption experiments showed that the sorption efficiency for Cr(VI) ions of the Sp-P[5] decreased to 70.88 % after 8 cycles. As result, the synthesized biosorbent, Sp-P[5], has outstanding potential in the removal of Cr(VI) ions from water bodies and natural wastewater systems.
Açıklama
PubMed ID 36220470
WOS:000897669100010
WOS:000897669100010
Anahtar Kelimeler
Biosorbent, Cr(VI), Microcapsule, Pillar[5]arene, Sporopollenin
Kaynak
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
857
Sayı
Künye
Bilgic, A., Cimen, A., & Kursunlu, A. N. (2023). A novel biosorbent functionalized pillar[5]arene: Synthesis, characterization and effective biosorption of cr(VI). Science of the Total Environment, 857 doi:10.1016/j.scitotenv.2022.159312
