Reversible NIR emitting fluorescent sensor with biocompatible and large Stokes shift for the Zn2+in environmental samples and living cells
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Tarih
2024
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Sci Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Herein, a simple dicyanoisophoron-based near-infrared (NIR) fluorescent sensor IQ has been designed and constructed for the rapid recognition of Zn2+ in environmental samples and living systems. The synthesized NIR sensor IQ in H2O/EtOH/ (1/9, v/v) displayed excellent recognition performances towards Zn2+ including nanomolar detection limit (60.5 nM) and a large Stokes shift (173 nm). Sensor IQ was successively applied to realize the determination of Zn2+ in smartphone applications. Furthermore, IQ-loaded test strips, cotton swabs, and polysulfone capsules were able to quickly determine the presence of Zn2+. Besides, IQ was effectively employed to monitor Zn2+ content in actual environmental samples (tap, pure, and lake water samples, rice, and potato). Additionally, the imaging potential of IQ was utilized to visualize Zn2+ in living cells. The results from these applications indicated that the designed probe IQ is hopeful to be utilized for the recognition of Zn2+ in multiple applications.
Açıklama
Anahtar Kelimeler
Fluorogenic sensor, Large Stokes shift, Near infrared, Zinc(II)
Kaynak
Measurement
WoS Q Değeri
N/A
Scopus Q Değeri
Q1
Cilt
235