Kamacı, MusaKaya, İsmet2019-12-062019-12-062013Kamacı, M., Kaya, İ. Synthesis of metal-coordinated poly(azomethine-urethane)s: Thermal stability, optical and electrochemical properties.Journal of Inorganic and Organometallic Polymers and Materials 23, 1159–1171 (2013).1574-1443https://dx.doi.org/10.1007/s10904-013-9908-8https://hdl.handle.net/11492/3172WOS:000322667700015In this study, the novel thermally stable metal-coordinated-poly(azomethine-urethane)s (PAMU-M)s were synthesized to investigate some physical properties such as thermal stability, optical and electrochemical properties. For this reason, we firstly synthesized the Schiff base via condensation reaction of p-phenylenediamine with 2,4-dihydroxy benzaldehyde. Secondly, metal-coordinated Schiff bases were synthesized by coordination reaction of the obtained Schiff base and different metal ions such as Cu(II), Ni(II), Pb(II) and Zn(II). Then, these metal-coordinated Schiff bases were converted to their PAMU derivatives by the step-polymerization reaction using 2,4-toluenediisocyanate. Also, thermal stability, electrochemical and optic properties of the obtained materials were investigated.enThermal PropertiesOptical PropertiesLuminescenceElectrochemical PropertiesPolymers-MetalsArticle23511591171info:eu-repo/semantics/closedAccess2-s2.0-84881025146WOS:00032266770001510.1007/s10904-013-9908-8Q1Q3