Electrochromic copolymers of 2,5-dithienyl-N-substituted-pyrrole (SNS) derivatives with EDOT: Properties and electrochromic device applications

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dc.authorid0000-0002-4178-5911en_US
dc.contributor.authorCansu Ergün, Emine Gül
dc.contributor.authorÇarbaş, Buket Bezgin
dc.date.accessioned2022-07-05T12:49:54Z
dc.date.available2022-07-05T12:49:54Z
dc.date.issued2022en_US
dc.departmentKMÜ, Mühendislik Fakültesi, Enerji Sistemleri Mühendisliği Bölümüen_US
dc.descriptionWOS:000861583100002en_US
dc.description.abstract2,5-dithienyl-N-substituted-pyrrole (SNS) derivatives are one of the most preferred conjugated systems for obtaining conducting polymers since they have low oxidation potential and ease of electrochemical polymerization. SNS backbone can be substituted from the nitrogen atom on the pyrrole unit and resulting SNS derivatives allow fine tuning on the spectroelectrochemical properties. Moreover, copolymerization of SNS derivatives leads to further tuning or enhancement on the features of the obtained copolymer. 3,4-Ethylenedioxythiophene (EDOT) is the most promising conjugated unit used in copolymerization of conjugated systems. In this review, electrochemically synthesized conducting copolymers of SNS derivatives with EDOT in the literature were collected and discussed. According to N-substitutions, SNS derivatives in copolymers were grouped into four sections: phenyl-, amine-, alkyl-, and crosslinked- substituted derivatives. In each section, the effect of different substitutions and amount of EDOT incorporation on the electrochromic properties of the resulting copolymers were both evaluated in the text and summarized in the tables. Electrochromic device applications, if exist, of related copolymers were also discussed. Here, an overview is presented of available electrochromic copolymers for SNS derivatives with EDOT, providing a perspective for scientists aiming to design new SNS derivatives for copolymerization.en_US
dc.identifier.citationCansu Ergün, E. G., & Bezgin Carbas, B. (2022). Electrochromic copolymers of 2,5-dithienyl-N-substituted-pyrrole (SNS) derivatives with EDOT: Properties and electrochromic device applications. Materials Today Communications, 32 doi:10.1016/j.mtcomm.2022.103888en_US
dc.identifier.doi10.1016/j.mtcomm.2022.103888
dc.identifier.issn2352-4928
dc.identifier.scopus2-s2.0-85132873570
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.mtcomm.2022.103888
dc.identifier.urihttps://hdl.handle.net/11492/6431
dc.identifier.volume32en_US
dc.identifier.wosWOS:000861583100002
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorÇarbaş, Buket Bezgin
dc.language.isoen
dc.publisherElsevier Ltd.en_US
dc.relation.journalMaterials Today Communicationsen_US
dc.relation.publicationcategoryDiğeren_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2,5-Dithienylpyrroleen_US
dc.subject3,4-Ethylenedioxythiopheneen_US
dc.subjectEDOTen_US
dc.subjectElectrochemical Copolymerizationen_US
dc.subjectElectrochromic polymersen_US
dc.subjectSNSen_US
dc.titleElectrochromic copolymers of 2,5-dithienyl-N-substituted-pyrrole (SNS) derivatives with EDOT: Properties and electrochromic device applicationsen_US
dc.typeOther

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