Rhodamine-based electrospun polyacrylonitrile (pan) nanofiber sensor for the detection of chlorinated hydrocarbon vapors

Basit Öğe Kaydı
dc.authoridÇapan, Rıfat/0000-0003-3222-9056
dc.contributor.authorÇapan, Rıfat
dc.contributor.authorÇapan, İnci
dc.contributor.authorBayrakçı, Mevlüt
dc.date.accessioned2025-01-12T17:19:47Z
dc.date.available2025-01-12T17:19:47Z
dc.date.issued2024
dc.departmentKMÜ, Mühendislik Fakültesi, Biyomühendislik Bölümü
dc.description.abstractThis study is the first report on the fabrication of polyacrylonitrile (PAN) nanofiber with rhodamine-based chemosensor (RHE) onto a mass-sensitive quartz crystal substrate using the electrospinning method and its sensing capability toward chlorinated hydrocarbons. Fabricated nanofiber webs via the electrospinning process are characterized by Fourier Transform Infrared (FTIR-ATR), Scanning Electron Microscopy, and Contact Angle measurement techniques, respectively. In order to investigate the vapor sensor properties, a Quartz Crystal Microbalance (QCM) system is employed to collect the real-time experimental data when the nanofiber sensor PAN-RHE is exposed to chlorinated hydrocarbons. Pseudo first-order and Elovich models are applied to elucidate the adsorption behavior. The morphological characterization proved smooth surface morphology without bead formation for all fibers with uniformity in the fiber skeleton. The average diameters of neat PAN and PAN nanofibers with RHE are found to be 449 and 790 nm, respectively. The nanofiber sensor PAN-RHE exhibits excellent sensing characteristics, including a high sensitivity of 0.0276 Hz/ppm, response and recovery times of 2-3 and 5-7 s, respectively, high selectivity for chloroform compared to other vapors tested, a limit of detection (LOD) of about 119.56 ppm, and a limit of quantification (LOQ) of about 362.31 ppm with a good reproducibility. The Pseudo-first-order adsorption rate and the Elovich desorption constants are determined as a function of different concentrations. The results obtained suggest that the QCM-based nanofiber sensor PAN-RHE shows great potential for the design of highly sensitive and selective chloroform sensors.
dc.identifier.citationÇapan, R., Çapan, I., & Bayrakçı, M. (2024). Rhodamine-based electrospun polyacrylonitrile (pan) nanofiber sensor for the detection of chlorinated hydrocarbon vapors. ACS Applied Polymer Materials, 6(13), 7500–7511. https://doi.org/10.1021/acsapm.4c00909
dc.identifier.doi10.1021/acsapm.4c00909
dc.identifier.issn2637-6105
dc.identifier.scopus2-s2.0-85196834271
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1021/acsapm.4c00909
dc.identifier.urihttps://hdl.handle.net/11492/10213
dc.identifier.wosWOS:001253300800001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Sceince
dc.indekslendigikaynakScopus
dc.institutionauthorBayrakçı, Mevlüt
dc.institutionauthoridBayrakçı, Mevlüt/0000-0002-0416-2870
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofAcs Applied Polymer Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20250111
dc.subjectrhodamine
dc.subjectpolyacrylonitrile
dc.subjectchlorinated hydrocarbonvapors
dc.subjectnanofiber
dc.subjectadsorption dynamics
dc.subjectQCM method
dc.titleRhodamine-based electrospun polyacrylonitrile (pan) nanofiber sensor for the detection of chlorinated hydrocarbon vapors
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Mühendislik Fakültesi, Biyomühendislik Bölümü, Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu