Highly efficient photocatalyst based on Zn2-xBaxSnO4 alloying nanoparticles with enhanced photocatalytic activity

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dc.contributor.authorKamo, Alaa
dc.contributor.authorSönmezoğlu, Özlem Ateş
dc.contributor.authorSönmezoğlu, Savaş
dc.date.accessioned2025-03-17T06:42:16Z
dc.date.available2025-03-17T06:42:16Z
dc.date.issued2025
dc.departmentKMÜ, Mühendislik Fakültesi, Biyomühendislik Bölümü
dc.departmentKMÜ, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü
dc.description.abstractIn this study, an effective Zn2-xBaxSnO4 alloying nanoparticles were hydrothermally designed with a series of barium cation as alloying dopant and utilized as a photocatalyst to decompose the rhodamine B which causes harmful effects on humans such as allergic dermatitis, skin irritation, mutation, and cancer. It is noteworthy that the Zn1.988Ba0.012SnO4 alloying-based catalyst exhibited more than 99 % degradation in only 140 min in wastewater than barium-free ternary oxide. Moreover, the reaction rate of Zn1.988Ba0.012SnO4 alloying-based catalyst was enhanced to 0.032 min-1 compared with barium-free ternary oxide (0.0179 min-1). Based on scavenger trapping experiments, hydroxyl radicals are the main reactive oxygen species responsible for photocatalytic activity of Zn1.988Ba0.012SnO4 alloying-based catalyst. Besides, the photocatalytic rate was maintained 94.89 % after 5th cycle. This research not only provides a novel strategy for developing alloying-based catalysts but also unveils their potential in photoelectrochemistry and photocatalysis.
dc.identifier.citationKamo, A., Sönmezoğlu, O. A., & Sönmezoğlu, S. (2025). Highly efficient photocatalyst based on Zn2-xBaxSnO4 alloying nanoparticles with enhanced photocatalytic activity. Inorganic Chemistry Communications, 174. https://doi.org/10.1016/j.inoche.2025.114080
dc.identifier.doi10.1016/j.inoche.2025.114080
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.issue2
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2025.114080
dc.identifier.urihttps://hdl.handle.net/11492/10634
dc.identifier.volume174
dc.identifier.wosWOS:001427874200001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorSönmezoğlu, Özlem Ateş
dc.institutionauthorSönmezoğlu, Savaş
dc.institutionauthoridSönmezoğlu, Özlem Ateş/0000-0002-3423-7095
dc.institutionauthoridSönmezoğlu, Savaş/0000-0002-6011-3504
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofInorganic Chemistry Communication
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAlloying-Based Photocatalyst
dc.subjectZinc Stannate
dc.subjectBa/Zn Gradient
dc.subjectMutagenic And Carcinogenic Pollutants
dc.subjectWastewater
dc.titleHighly efficient photocatalyst based on Zn2-xBaxSnO4 alloying nanoparticles with enhanced photocatalytic activity
dc.typeArticle

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